VaR is not a good measure of risk taking, in my opinion. It suffers from inherent faulty assumptions (check out VaR Wiki to start) and it omits many other important aspects of risk measurement.
When I evaluate an asset's risk and return I like to start looking at the following:
- Historical risk and returns of an asset. This leads to the Sharpe Ratio, though I prefer a slightly different ratio which does not penalize for excess performance to the upside (Sharpe Ratio does penalize)
- Expected returns and risk. Can I have confidence that historical risk and return figures are a reasonable predictor of future risk and return. If not then, is there a way to make adjustements? If not then I should not take into consideration historical risk and return values when evaluating future expected risk and returns.
- Drawdowns of an asset's return. Alongside the drawdown I want to know how long it took for the asset's subsequent returns to make it back to the pre-drawdown return.
- Correlation of the asset with other assets. Is the asset uncorrelated or potentially even negatively correlated with other assets?
- Contribution of the asset to the portfolio overall. Does the asset contribute to a lower portfolio risk and portfolio risk adjusted returns.
Regarding your points:
"How does one interpret volatility on its own": It is a measure of variation around a certain mean, either historically around a historical mean or around expected value. Standard deviation is expressed in percentage terms if it is calculated using returns as input. If you calculate volatility on prices or other metrics then you need to convert to percentage figures.
"What does the 1 unit of risk mean": The one unit of risk you refer to is in percentage terms so Sharpe Ratio expresses the excess return in percent per percent of risk. Its a very clear cut and simple way to comprehend risk, in my opinion.