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I think what you are missing is simply the Vega-Gamma relation in the Black-Scholes model. Namely: $$Vega = \frac{\partial v}{\partial \sigma} = \sigma(T-t)S^2 \frac{\partial^2 v}{\partial S^2} = \sigma \tau S^2 \Gamma$$ Plugging this into your coverage error, you get its expression in terms of the Vega which is the most natural measurement of your ...