It seems that you are thinking of the volatility as some sort of standard deviation of your stock price. It is not.
In the BS model, $\sigma\sqrt{T}$ is the standard deviation of the log-return $\log(\frac{S_T}{S_0})$. There is no mathematical upper bound to its standard deviation. There is also no mathematical problem with returns being negative either. Quoting volatility as a percentage is common practice but does not necessarily make sense (in stochastic volatility models, vol of vol parameters can often be calibrated to $\sim 300\%$).
Note that even a positive random variable's standard deviation can be much larger than its mean if its right tail is fat enough. Consider the family of lognormal distributions for example, the standard deviation can be arbitrary large for a given mean.