In the Black-Scholes world, it is assumed that the option value $C(t, S_t)$ is replicable by an admissible self-financing trading strategy $\phi$, where $\phi_t=(\alpha_t, \beta_t)$. That is,
\begin{align*}
C(t, S_t) = \alpha_t B_t + \beta_t S_t,
\end{align*}
and
\begin{align*}
dC(t, S_t) = \alpha_t dB_t + \beta_t dS_t.
\end{align*}
Since $dB_t = rB_t dt$, and $dS_t = S_t(rdt + \sigma dW_t)$, then
\begin{align*}
d\bigg(\frac{C(t, S_t)}{B_t} \bigg) &= \frac{dC(t, S_t)}{B_t}-\frac{C(t, S_t)}{B_t^2}dB_t\\
&=\beta_t \frac{dS_t}{B_t} - \beta_t \frac{S_t}{B_t^2}dB_t\\
&=\beta_t \frac{S_t(rdt + \sigma dW_t)}{B_t} - \beta_t \frac{S_t}{B_t}rdt\\
&=\sigma\beta_t\frac{S_t}{B_t}dW_t.
\end{align*}
Therefore, $\{C(t, S_t)/B_t \mid 0\leq t \leq T\}$ is a martingale.