The VaR of level $\alpha$ a loss random variable (the bigger the worse) is the quantity $q$ such that the loss is bigger with probability $1-\alpha$.
Thus we need a $q$ such that
$$
P[L>q] = 1-\alpha,
$$
where we can imagine $\alpha=99\%$ and thus we need the starting point of the $1\%$ tail. Because we have a probability of a loss of size $0$ of $75\%$ we have a discontinuity of the cdf there.
We have to analyze the cdf of $L$ in detail: Recalling that the density of an exponential rv is given by $\mu \exp(-\mu x)$ we get
$$
P[L \le q] = 0.75+0.25 \int_0^q \mu \exp(-\mu x) dx = 0.75 + 0.25(1- \exp(-\mu q)).
$$
For a given level $\alpha$ we can then solve
$$
\alpha = 0.75 + 0.25(1- \exp(-\mu q))
$$
by rearranging terms and get
$$
(\alpha-0.75)/0.25 = 1 - \exp(-\mu q)
$$
and finally
$$
q = -\frac{1}{\mu} \ln\left(1- (\alpha-0.75)/0.25 \right).
$$
For example for $\mu=1$ and $\alpha=0.99$ we get a VaR of $3.2189$ in the mixed case, whereas in the exponential case without the mass at zero it would be $-\ln(1-\alpha) = 4.6052$.