For an ATM call option, the vega is given by
\begin{align*}
\frac{\partial C}{\partial \sigma} &= SN'(d_1)\sqrt{T}\\
&=\frac{1}{\sqrt{2\pi}}S\,e^{-\frac{d_1^2}{2}}\sqrt{T}\\
&=\frac{1}{\sqrt{2\pi}}S\,e^{-\frac{\sigma^2}{8}T}\sqrt{T}.
\end{align*}
Then, the volga is given by
\begin{align*}
\frac{\partial^2 C}{\partial \sigma^2} &=-\frac{1}{4\sqrt{2\pi}}S\,e^{-\frac{\sigma^2}{8}T} \sigma\, T^{3/2},
\end{align*}
which is negative. That is, the vega does not increase with the volatility. Depending on the magnitude of $S$, $\sigma$, and $T$, the volga does not have to be insignificant. For example, for $S=100$, $\sigma=0.35$, and $T=5$,
\begin{align*}
\frac{\partial^2 C}{\partial \sigma^2} \approx -36.15,
\end{align*}
which does not appear small.