I assume no interest rates to clarify the approach. The Heston model is written under the risk-neutral probability as
$$ \frac{dS_t}{S_t} = \sqrt{v_t}dW_t $$
$$ dv_t = -\kappa(v_t-\eta)dt + \theta \sqrt{v_t}dZ_t $$
with $d\langle W,Z\rangle_t = \rho dt$ and $v_0 = \sigma_0^2$. Using Itô's lemma we can derive
$$ \log\left(\frac{S_t}{S_0}\right) = \int_0^t \sqrt{v_s}dW_s - \frac{1}{2} \int_0^t v_s ds $$
According to the CBOE white paper, the SKEW index is computed from
$$ SKEW = 100 - 10 \mathbb{E}\left[ \left(\frac{R-\mu}{\sigma}\right)^3\right]$$
with $R$ being the 30-day log return of the S&P500 and $\mu$, $\sigma$ its mean and variance. You can -not without some work- rewrite the SKEW as a function of $v_t$ moments. Indeed you will have to use :
- Itô's lemma with $f(x)=x^\alpha$ to get $\mathbb{E}(X_t^\alpha)$ with $X_t := \int_0^t \sqrt{v_s} dW_s$
- Itô's lemma with $f(x,y)=xy$ to get mixed expectation of form $\mathbb{E}(X_t^\alpha v_t^\beta)$
Eventually you will only worry about finding $v_t$ moments, which can be obtained by using the classical
$$v_t - \mathbb{E}(v_t) = \theta\int_0^t e^{-k(t-s)}\sqrt{v_s}dW_s $$
and the above.
In case you need fractional moments (as you are looking at the VIX as well), the following should be of interest.
Let X be a random variable with Laplace transform $\mathcal{L}$. Then if $n\in\mathbb{N}$ and $\alpha>0$ then
$$ \mathbb{E}[X^{n-\alpha}] = \frac{(-1)^n}{\Gamma(\alpha)}\int_0^\infty \frac{\partial^{(n)}\mathcal{L}}{\partial \lambda}(\lambda)\lambda^{\alpha-1}d\lambda $$
This can be applied to find $\mathbb{E}[\sqrt{v_t}]$, $\mathbb{E}[v_t^{3/2}]$, etc. The Laplace transform of a CIR process has a closed-form of affine type and can be easily found in the litterature.