@Ivan's comment regarding the covariances is the key.
Consider an equally spaced partition $\Pi_n = \left\{ t_0 = 0, t_1 = \Delta_n, \ldots, t_n = t \right\}$ of the interval $[0, t]$, where $t_i = i \Delta_n$ and $\Delta_n = t / n$ so that
\begin{equation}
X_t = \lim_{n \rightarrow \infty} X_n, \qquad X_n = \sum_{i = 1}^n W_{t_i} \left( t_i - t_{i - 1} \right). \nonumber
\end{equation}
Now, each $W_{t_i}$ is $\mathcal{N} \left( 0, t_i \right)$ distributed and the covariance between $W_{t_i}$ and $W_{t_j}$ for $i, j \in \{ 0, 1, \ldots, n \}$ is $\min \left\{ t_i, t_j \right\} = \Delta \min \{ i, j \}$. Let $\bar{W}_n = \left( \begin{array}{c c c c} W_{t_1} & W_{t_2} & \dots & W_{t_n} \end{array} \right)'$, then the covariance matrix is
\begin{eqnarray}
\bar{\Sigma}_n = \mathbb{E} \left[ \bar{W}_n \bar{W}_n' \right] = \left[ \begin{array}{c c c c} t_1 & t_1 & \dots & t_1\\ t_1 & t_2 & \dots & t_2\\ t_1 & t_2 & \ddots & \vdots\\ t_1 & t_2 & \dots & t_n \end{array} \right] = \Delta_n \left[ \begin{array}{c c c c} 1 & 1 & \dots & 1\\ 1 & 2 & \dots & 2\\ 1 & 2 & \ddots & \vdots\\ 1 & 2 & \dots & n \end{array} \right]. \nonumber
\end{eqnarray}
As the weighted sum of normally distributed random variables is itself normally distributed, it follows that $X_n \sim \mathcal{N} \left( 0, \Delta_n \bar{1}_n \bar{\Sigma}_n \bar{1}_n' \Delta_n \right)$, where $\bar{1}_n$ is an $n$-dimensional column vector of ones. We have
\begin{eqnarray}
\text{Var} \left( X_n \right) & = & \Delta_n^3 \sum_{i = 1}^n i \left( 2 (n - i) + 1 \right) \nonumber\\
& = & \Delta_n^3 \left( \frac{1}{3} n^3 + \frac{1}{2} n^2 + \frac{1}{6} n \right) \nonumber\\
& = & t^3 \left( \frac{1}{3} + \frac{1}{2} n^{-1} + \frac{1}{6} n^{-2} \right). \nonumber
\end{eqnarray}
Consequently,
\begin{equation}
\lim_{n \rightarrow \infty} \text{Var} \left( X_n \right) = \frac{1}{3} t^3 \nonumber
\end{equation}
and it follows that $X_t \sim \mathcal{N} \left( 0, t^3 / 3 \right)$.