The approximation is:
$$\sigma \approx \frac{\sum V_j\sigma_j}{\sum V_j}$$
Background information from the first answer to this post:
"Say that you have a portfolio of options with prices $P_j$. Each one of them has a different pricing function $f_j$ (as function of vol) and a different implied vol $\sigma_j$. For each option $f_j(\sigma_j)=P_j$.
Now you put them together in a single product. If the implied vol of the product is $\sigma$ then $\sum f_j(\sigma)=\sum P_j$. Now, approximately each pricing function will satisfy $f_j(\sigma)\approx P_j+V_j (\sigma-\sigma_j)$ as a linear expansion around its price, with $V_j$ the Vega."