You cannot derive the probability distribution you require, because for VaR you need a real-world probability distribution. From the options prices, it is only possible to obtain a risk-neutral distribution.
Now, if you are willing to assume some kind of parametric relationship between the risk-neutral and real-world distributions, then you might find the options prices useful. The resulting mathematics for a stochastic volatility model is somewhat tricky, however. You can find most of it in Jim Gatheral's books. A sloppy treatment would just take the risk-neutral distribution and shift its mean.
Obtaining the approximate risk-neutral distribution is fairly simple. Let p(S) be the time-T risk-neutral probability density. Then we see that (TeX notation alert)
\begin{equation}
C := Call(T) = B(0,T) \int_0^\infty Max(0,S-K) p(S) dS
\end{equation}
\begin{equation}
\frac{dC}{dK} = B(0,T) \int_0^\infty 1[S>=K] (-1) p(S) dS \qquad\text{[differentiate under integral] }
\end{equation}
\begin{equation}
\frac{dC}{dK} = B(0,T) \int_K^\infty (-1) p(S) dS
\end{equation}
\begin{equation}
\frac{d^2C}{dK^2} = B(0,T) p(K) \qquad \text{ [Fundamental thm of calculus]}
\end{equation}
Alternatively, you could say that p(S) is the density, and is the derivative of the cumulative distribution function P(S), and write
\begin{equation}
C := Call(T) = B(0,T) \int_0^\infty Max(0,S-K) p(S) dS
\end{equation}
\begin{equation}
\frac{dC}{dK} = B(0,T) \int_0^\infty 1[S>=K] (-1) p(S) dS \qquad\text{[differentiate under integral] }
\end{equation}
\begin{equation}
\frac{dC}{dK} = B(0,T) \int_K^\infty (-1) p(S) dS
\end{equation}
\begin{equation}
\frac{dC}{dK} = B(0,T) (-1) ( P(\infty) - P(K))
\end{equation}
\begin{equation}
\frac{d^2C}{dK^2} = B(0,T) p(K)
\end{equation}
Either way you end up finding the density
\begin{equation}
p(x) = \frac{1}{B(0,T)} \frac{d^2C(x)}{dx^2}
\end{equation}
where $x$ is the strike. So an approximate density comes from using the actual option prices available to you. You can spline interpolate, or if you have a regular grid of strikes spaced by dK you can make a histogram of values
\begin{equation}
\frac{ C(K+dK) - 2C(K) +C(K-dK) }{ dK^2}
\end{equation}
and divide by the discount factor to find your risk-neutral distribution.